方法一
Method 1
硫酸鉀法用硫酸銨和硫酸配制成電解液除雜質(zhì)后進(jìn)行電解。HSO4在陽極放電而生成過二硫酸，再與硫酸銨反應(yīng)生成過硫酸銨，然后加入硫酸鉀進(jìn)行復(fù)分解反應(yīng)，經(jīng)冷卻、分離、結(jié)晶、干燥，制得過硫酸鉀成品。其
The potassium sulfate method uses ammonium sulfate and sulfuric acid to prepare an electrolyte for electrolysis after removing impurities. HSO4 is discharged at the anode to produce persulfate, and then reacts with ammonium sulfate to produce ammonium persulfate, then potassium sulfate is added for double decomposition reaction, and the finished product of potassium persulfate is prepared through cooling, separation, crystallization and drying. his
陽極反應(yīng)：2HSO4-2e→H2S2O8
Anode reaction: 2hso4-2e → h2s2o8
陰極反應(yīng)：2H+2e→H2↑
Cathode reaction: 2h + 2e → H2 ↑
(NH4)2SO4+H2S2O8→(NH4)2S2O8+H2SO4
(NH4)2SO4+H2S2O8→(NH4)2S2O8+H2SO4
(NH4)2S2O8+K2SO4+H2SO4→K2S2O8+2NH4HSO4
(NH4)2S2O8+K2SO4+H2SO4→K2S2O8+2NH4HSO4
方法二
Method 2
由過硫酸銨與硫酸鉀進(jìn)行復(fù)分解反應(yīng)后，冷卻、分離、結(jié)晶、干燥而得。
It is obtained by double decomposition reaction of ammonium persulfate and potassium sulfate, cooling, separation, crystallization and drying.
過硫酸鉀用途
Application of potassium persulfate
過硫酸鉀可用作油井壓裂液的破膠劑。在合成樹脂、合成橡膠工業(yè)中作為乳液聚合的引發(fā)劑,用于丁二烯苯乙烯橡膠的合成;在照相業(yè)中用作硫代硫酸鈉的脫除劑;染料和印染工業(yè)中用作氧化劑;油脂工業(yè)中作漂白劑等。
Potassium persulfate can be used as gel breaker for oil well fracturing fluid. In the synthetic resin and synthetic rubber industry, it is used as initiator of emulsion polymerization for the synthesis of butadiene styrene rubber. Used as a remover of sodium thiosulfate in the photographic industry; Used as oxidant in dye and printing and dyeing industry; Used as bleaching agent in oil industry.
過硫酸鉀注意事項(xiàng)
Precautions for potassium persulfate
操作注意事項(xiàng):密閉操作，加強(qiáng)通風(fēng)。操作人員必須經(jīng)過專門培訓(xùn)，嚴(yán)格遵守操作規(guī)程。建議操作人員佩戴頭罩型電動(dòng)送風(fēng)過濾式防塵呼吸器，穿聚乙烯防毒服，戴橡膠手套。遠(yuǎn)離火種、熱源，工作場所嚴(yán)禁吸煙。避免產(chǎn)生粉塵。避免與還原劑、活性金屬粉末、堿類、醇類接觸。搬運(yùn)時(shí)要輕裝輕卸，防止包裝及容器損壞。禁止震動(dòng)、撞擊和摩擦。配備相應(yīng)品種和數(shù)量的消防器材及泄漏應(yīng)急處理設(shè)備。倒空的容器可能殘留有害物。
Precautions for operation: close operation and strengthen ventilation. Operators must receive special training and strictly abide by the operating procedures. It is recommended that operators wear hooded electric air supply filter dust respirator, polyethylene anti-virus clothing and rubber gloves. Keep away from kindling and heat sources. Smoking is strictly prohibited in the workplace. Avoid dust generation. Avoid contact with reducing agent, active metal powder, alkali and alcohol. Handle with care to prevent damage to packaging and containers. Vibration, impact and friction are prohibited. Provide corresponding varieties and quantities of fire-fighting equipment and leakage emergency treatment equipment. Emptied containers may leave harmful substances.
儲(chǔ)存注意事項(xiàng):儲(chǔ)存于陰涼、干燥、通風(fēng)良好的庫房。遠(yuǎn)離火種、熱源。包裝密封。應(yīng)與還原劑、活性金屬粉末、堿類、醇類等分開存放，切忌混儲(chǔ)。儲(chǔ)區(qū)應(yīng)備有合適的材料收容泄漏物。
Storage precautions: store in a cool, dry and well ventilated warehouse. Keep away from fire and heat source. Packing and sealing. It shall be stored separately from reducing agent, active metal powder, alkali, alcohol, etc., and mixed storage shall not be allowed. The storage area shall be provided with suitable materials to contain leakage.
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